ChemInform Abstract: Geometric Equivalents of Enantiomers in Studies of the Stereochemical Course of Substitution at Carbon. Electronic Effects in Nucleophilic Addition to Carbonyl Groups and to Carbocations. Virtual Proof of the Existence of σ Participation by Unstrained Carbon ‐ Carbon Bonds.

C K Cheung,W J Le Noble,S Srivastava,L T Tseng,M.‐H Lin

doi:10.1002/chin.198630092

ChemInform Abstract: Geometric Equivalents of Enantiomers in Studies of the Stereochemical Course of Substitution at Carbon. Electronic Effects in Nucleophilic Addition to Carbonyl Groups and to Carbocations. Virtual Proof of the Existence of σ Participation by Unstrained Carbon ‐ Carbon Bonds.

C K Cheung, W J Le Noble + Show 3 more

https://doi.org/10.1002/chin.198630092

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Journal: Chemischer Informationsdienst

Publication Date: Jul 29, 1986

#Course Of Substitution #Carbon Bonds + Show 7 more

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AbstractAdamantones (1) with electron‐withdrawing S‐substitucnts favor syn‐addition of nucleophiles while donating groups in this position lead to favored anti‐approach.

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