Abstract
The reactions of benzene derivatives C6H5X (X = H, Cl, CH3 and CF3) with hydrazine and ozone in the dark (a source of OH radicals) have been studied in a flow reactor at ambient temperature. (Substituted) phenols were formed, but these were relatively unimportant compared to N-heterocyclic compounds (condensation products of cis-butenedial and analogues with hydrazine) and other (degradation) products. Benzene and (trifluoromethyl)benzene follow a similar path as toluene, also with oxidative ring opening as major reactions.
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