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https://doi.org/10.1002/chin.201226034
Copy DOIJournal: ChemInform | Publication Date: May 31, 2012 |
Abstract Oxovanadium(V) complex 4 was prepared from VOSO 4 and tridentate Schiff base ligand, which was prepared from substituted salicylaldehyde and inexpensive ( S )-valine. Asymmetric silylcyanation of the aldehydes catalyzed by catalyst 4 afforded cyanohydrins with good enantioselectivities.
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