ChemInform Abstract: Enantiodivergent Hydroboration Reactions of a Racemic Allenylsilane with Diisopinocampheylborane and Curtin—Hammett Controlled Double Asymmetric Crotylboration Reactions of (S)‐E‐α‐Phenyldimethylsilyl (ddiisopinocampheyl)‐crotylborane.

Ming Chen, William R Roush

https://doi.org/10.1002/chin.201345023

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Publication Date: Oct 14, 2013

Abstract

AbstractThe title reaction offers a convenient access to chiral homoallylic alcohols having a silyl substituent at the terminal olefin carbon.

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