Abstract
Abstract Ca(BH2S3)2 is easily prepared by metathetical reaction between NaBH2S3 and CaCl2 in THF. Ca(BH2S3)2 is much more stable than NaBH2S3 therefore, is a more practical reagent. Sulfurated calcium borohydride can easily reduce aryl nitro and aryl azido functions to their amines in high yields in refluxing THF. Reduction of nitro groups is accompanied with regioselectivity. Very high chemoselectivity is also observed for the reduction of an azido functional group in the presence of nitro functionality.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
