Abstract
The dynamics of the thermal decomposition of 2,3-diazabicyclo [2.2.1] hept-2-ene (DBH) have been investigated over the temperature range 900-1400 K. A tunable continuous wave CO laser was used to follow the vibrational energy content of the coupled CO−N 2 system from the initial to the equilibrium conditions. It has been shown that the N 2 is born with very little vibrational energy, while the bicyclo [2.1.0] pentane is born with an excess over the equilibrium distribution. These results provide clear evidence against the concerted decomposition mechanism
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