ChemInform Abstract: Dioxygen‐Copper Reactivity. Models for Hemocyanin: Reversible O2 and CO Binding to Structurally Characterized Dicopper(I) Complexes Containing Hydrocarbon‐Linked Bis(2‐(2‐pyridyl)ethyl)amine Units.

K D Karlin,J C Hayes,Y Gultneh,A Farooq,R W Cruse,G J Meyer,M S Haka,J Zubieta

doi:10.1002/chin.198823300

ChemInform Abstract: Dioxygen‐Copper Reactivity. Models for Hemocyanin: Reversible O2 and CO Binding to Structurally Characterized Dicopper(I) Complexes Containing Hydrocarbon‐Linked Bis(2‐(2‐pyridyl)ethyl)amine Units.

K D Karlin, J C Hayes + Show 6 more

https://doi.org/10.1002/chin.198823300

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Journal: ChemInform

Publication Date: Jun 7, 1988

Affiliation: Albany State University

#Reversible O2 #Amine Units + Show 6 more

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Abstract

AbstractThe dinucleating ligand is prepared from excess 2‐vinylpyridine and 1,4‐diaminobutane in an acid‐catalyzed reaction (70 to 80% yield) and reacts with (Cu(MeCN)4)Y (Y: PF6‐ or ClO4‐) in CO‐saturated MeOH to give (Ia).

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