Abstract
Abstract Alkylation of the anion of the title compound with iodomethane, benzylbromide, or allyl bromide proceeds in a highly diastereoselective fashion to afford tricarbonyl(2S*,3R* methyl 2-substituted-3,5-hexadienoate) iron complexes. The relative stereochemistry of the methylation product 2a was determined by single X-ray crystallographic analysis of the corresponding diastereomeric carboxylic acid 4b.
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