ChemInform Abstract: Covalently Anchored n‐Propyl‐4‐aza‐1‐azoniabicyclo[2.2.2]octane Chloride on SBA‐15 as a Basic Nanocatalyst for the Synthesis of Pyran Heterocyclic Compounds.

Abstract

In the present study, highly ordered n-propyl-1,4 diazoniabicycle[2.2.2]octane chloride functionalized mesoporous SBA-15, SBA-DABCO, with high surface area and narrow pore-size distribution was synthesized and characterized by TEM, SEM, FT-IR, CHN, TGA, XRD and BET. The organic-modified SBA-15 has hexagonal crystallographic order, pore diameter up to 54.2 A, and the content of DABCO groups up to 1.38 mmol g−1. The catalyst shows an environmentally benign character, which can be easily prepared, stored and recovered without obvious significant loss of activity. The synthesized basic organocatalyst provides a green and useful method for the one-pot synthesis of pyran annulated heterocyclic compounds, and especially spirooxindole pyran compounds in aqueous media. The significant features of the present protocol are simple, environmentally benign, high yields, no chromatographic separation and recyclability of the catalyst.