Abstract
Abstract. Solid state monomeric structures with monometallic biconnective (bidentate) diphenylphosphinodithioato groups were found in Ph2Te(S2PPh2)2 (1) or [Ph3Te][S2PPh2] (2), while in the polymeric associations [Te2(S2PPh2)2]n (3) and [PhTeS(S)PPh2]n (4) bimetallic biconnective (bridging) and monodentate biconnective (bridging) patterns were established by X-ray diffractometry. [Te(S2PPh2)3]2 (5) exhibits an unusual dimeric structure, with both monometallic biconnective and bimetallic triconnective ligand units.
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