Abstract
Abstract 1,4-addition of hydride to quinone monoketals 1 and p -quinol ethers 2, mediated by bis-(2,6-di- t -butyl-4-methylphenoxy)-methylaluminum (MAD), affords 4,4-substituted-2-cyclohexen-1-ones 3, which represent keto-tautomer equivalents of phenols.
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