ChemInform Abstract: Complexes with Functional Phosphines. Part 12. Carbon‐Carbon Coupling Reactions by Isocyanate Insertion into Nickel‐, Palladium‐, and Platinum‐Coordinated β‐Phosphino Enolates. Molecular Structures of Cyclic ((C10H8N)Pd(Ph2PC(C(O)OEt)(=C(O)NHPh))) and Cyclic cis‐(Ni(Ph2PC(C(O)Ph)(=C(O)NH(p‐MeC6H4)))2)·CH2Cl2.

S.‐E Bouaoud,D Nobel,D Matt,P Braunstein,D Grandjean

doi:10.1002/chin.198844295

ChemInform Abstract: Complexes with Functional Phosphines. Part 12. Carbon‐Carbon Coupling Reactions by Isocyanate Insertion into Nickel‐, Palladium‐, and Platinum‐Coordinated β‐Phosphino Enolates. Molecular Structures of Cyclic ((C10H8N)Pd(Ph2PC(C(O)OEt)(=C(O)NHPh))) and Cyclic cis‐(Ni(Ph2PC(C(O)Ph)(=C(O)NH(p‐MeC6H4)))2)·CH2Cl2.

S.‐E Bouaoud, D Nobel + Show 3 more

https://doi.org/10.1002/chin.198844295

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Journal: ChemInform

Publication Date: Nov 1, 1988

#Reaction Of Phenyl Isocyanate #Coupling Products + Show 3 more

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Abstract

AbstractThe reaction of phenyl isocyanate with the Pd complexes (Ia), (Ib) and (Va) affords the corresponding complexes (III) and (VI), whereas starting with (Ic) or (Vb) two coupling products, (IIIc) and (IVc) or (VIb) and (VIIb), are obtained which are in equilibrium.

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