Abstract

AbstractAufgrund von elektronen‐ und NMR‐spektroskopischen Untersuchungen und Vergleichen mit analogen Histamin‐Cu(II)‐Systemen wird angenommen, daß Cu(II) mit einem Überschuß an Histidin in Abwesenheit von Base vorherrschend die 1:2‐Aquo‐Komplexe (I) und (II) bildet und in Gegenwart von 1 und 2 Molen KOH der neutrale Bis‐[histidinato]‐Cu‐Komplex (III) entsteht.

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