Abstract
AbstractThe discovery of the 12‐electron clusters (I) (by‐product in the synthesis of W4H2(OiPr)14) and (II) (by‐product in the thermal decomposition of W4(OiPr)12 in hydrocarbon solvents) has afforded insights into the complementary bonding in clusters of early and late transition‐metals with alkoxide and carbonyl ligands, respectively.
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