Abstract

The sequence of ortho-directing abilities of a series of aryl functionalities in arenetricarbonylchromium(0) complexes has been shown to be different to that in the uncomplexed arenes. The kinetic resolution of the lithiated complexes with homochiral oxazolidinones has been rationalised via a transition state model and applied to the stereocontrolled synthesis of a series of highly functionalised, homochiral phenethylamines.

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