Abstract

AbstractThe oxygen‐stoichiometric, B‐site‐ordered perovskite Ca2Fe1.1Mn0.9O6 with alternate stacking of Fe and Mn layers is prepared by reaction of Ca2Fe1.1Mn0.9O5 with KClO4 in a molar ratio of 1:0.5 (gold foil, 4 GPa, 550 °C, 45 min).

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