Abstract

Abstract The reaction between (C5Me5)SiMe3 and group 4 element tetrahalides MX4 (M  Ti, X  Cl, Br, I; M  Zr and Hf, X  Cl) gives the corresponding (η5-C5Me5)MX3 derivatives in nearly quantitative yields in a one-step procedure without the need for further purification.

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