Abstract
AbstractDomino Mannich—aza‐Michael reaction of aromatic N‐Boc‐protected aldimines (II) with ene tetracarboxylate (I) is efficiently catalyzed by a chiral bifunctional thiourea catalyst to give polyfunctionalized pyrrolidines (III) in good yields and stereoselectivities (<95% d.e., up to 94% e.e.).
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