Abstract
AbstractA three‐component, domino Michael—Michael—Michael—aldol process of the indole‐derived substrates of the type (I) with two identical or different molecules of α,β‐unsaturated aldehydes under quadruple iminium/enamine/iminium/enamine catalysis affords a variety of the enantiomerically pure hydroindane derivatives, bearing six contiguous stereocenters and a spirooxindole motif with complete diastereoselectivities [cf.
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