Abstract

Dimethylaluminum chloride and ethylaluminum sesquichloride catalyze the ene reactions of formaldehyde with the C,C-double bond of unsaturated carboxylic acids, for example oleic acid and 10-undecenoic acid, and of the respective alcohols. Ethylaluminum dichloride catalyzes the ene reactions of formaldehyde with the respective carboxylic acid esters

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