Abstract

AbstractNitrenoformates, e.g. (IV), are generated a) by thermolysis (vapour‐phase (spray) pyrolysis or solution thermolysis) of azidoformates such as (Ia)/(Ib), (Ie), (If), (IXa), (IXb), (XIVa), (XIVb) or b) by photolysis of respective tetrachlorothienyl S,N‐ylides such as (Ic)/(Id).

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