Abstract

Photoreduction of dialkyl sulfoxides (R 2 SO) by an acid-stable NADH analogue, 10-methyl-9,10-dihydroacridine (AcrH 2 ), proceeds in the presence of perchloric acid in acetonitrile containing H 2 O (0.50 M) to yield 10-methylacridinium ion (AcrH + ) and the corresponding dialkyl sulfides (R 2 S). No photoreduction of R 2 SO by AcrH 2 has occurred in the absence of perchloric acid

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