Abstract
The intermolecular Diels-Alder reaction in which either the diene or the dienophile carries a suitably located homolyzable substituent, such as a phenylseleno group, represents a convenient method for assembly of compounds that can undergo radical cyclization. The technique can be used to generate polycyclic structures that are fused in a linear, bridged, or spiro manner. The hetero Diels-Alder version is equally versatile in this connection
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