Abstract
In the absence of a ligand and in non-coordinating solvents, Os6(CO)18 racts with 2 equivalents of R3No (R = Me, Et) to give the new hexaosmium cluster [HOs6(CO)17]−. Variable temperature 1H and 13C NMR and 2D NMR. techniques have been used to investigate the structure of this anion and its dynamic behviour in solution. The mechanism of the novel reaction is discussed.
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