Abstract
The cadmium complex of an expanded five-coordinate porphyrin known as texaphyrin and its complexes with pyridine and benzimidazole have been investigated by solution- and solid-state {sup 113}Cd NMR spectroscopy, and the results are reported. The principle shielding tensor elements were determined for each complex and are discussed in terms of reported crystal studies of Cd-texaphyrin and in comparison to cadmium complexes with other porphyrin and similar macrocycle ligands. 18 refs., 5 figs., 1 tab.
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