Abstract
AbstractCIDNP has been found for the methylene protons in Ph3CR (R = C6H5CH2) from the reaction of RHg with Ph3CX. A weak CIDNP effect was observed in the product (CH3O)2C6H3CPh3 of alkylation of veratrol by Ph3CCl (an aromatic SE substitution) and in the Meisenheimer complex resulting from the reaction of (CH3COCH2)2Hg with trinitrobenzene in DMSO in the presence of iodide ions (an aromatic SN substitution).
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