Abstract

1. Nueleophilic reagents add to the 2-alkoxyacroleins in the 1,2 position. Together with nucleophilic addition at the carbonyl group, hydration of the C=C bond occurs in the presence of acid catalysts. 2. Based on the reaction of 2-alkoxyacroleins with Grignard reagent, a new method was proposed for the preparation of acetoin and its homologs, and also a method for the synthesis of a new type of vinyl ethers, and specifically theα-hydroxyalkylvinyl alkyl ethers.

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