Abstract
1. The action of nucleophilic and electrophilic reagents on the dichloromethyl group was studied on the example of 1,1-dichloroheptane. 2. The dichloromethyl group is more inert toward the action of nucleophilic reagents than the chloromethyl group; only under the action of such strong nucleophiles as sodium thiophenolate could both of the chlorine atoms be replaced. 3. The dichloromethyl group, in contrast to the trichloromethyl group, isinert toward the action of such electrophilic reagents as concd. sulfuric and anhydrous nitric acids. However, compounds containing the dichloromethyl group are capable of condensing with benzene in the presence of aluminum chloride.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
