Abstract
Some coenzyme A analogs, such as α-methyl-(IVc), β-methyl-(IVd), and α-carboxy-coenzyme A (IVe), have been synthesized from the nitrile compound (Ib) and cysteamine derivatives (IIc–e) via the respective thiazoline intermediates (IIIc–e). Homo-coenzyme A (XII) has been synthesized by a combination of the methods of Moffatt and Khorana, for the formation of pyrophosphate, and Michelson, for 2′, 3′-cyclic phosphate fission.
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