Chemical Recycling of Poly(bisphenol A carbonate) by Glycolysis under 1,8-Diazabicyclo[5.4.0]undec-7-ene Catalysis.

Abstract

The glycolysis reaction of poly(bisphenol A carbonate) (PC) has been explored under 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) catalysis as a potential route to valorize PC wastes by chemical recycling. The amidine base is an active catalyst of PC glycolysis and, under suitable conditions, promotes effectively and selectively the depolymerization of the polymeric material with 1,2-propanediol or glycerol to give the monomer bisphenol A (BPA) and the relevant cyclic carbonate. The depolymerization process has been investigated under solventless conditions, using diol/triol as the reagent and reaction medium, and also in an auxiliary solvent such as tetrahydrofuran (THF) that is able to dissolve the polymer. The influence of a few experimental parameters (temperature, catalyst load, and reaction time) on the selectivity to cyclic carbonate has been studied. High selectivity to cyclic carbonate has been attained by carrying out the depolymerization reaction in THF and using mild temperature conditions and a stoichiometric amount of polyol. The catalyst can be recovered from the reaction mixture as a BPA/DBU adduct and effectively recycled in a successive run.