Abstract
In this theory a chemical reaction is treated as a quantum transition from reactants to products. The approach leads to a Franck–Condon-like factor for the evaluation of product energy distributions. Second-quantization representation is used to enable a Hamiltonian for reaction to be defined. A specific adiabatic method is used to describe the dynamics of nuclear motion. The theory is applied to the reactions HO + D OD + H and ClI + D Cl + ID. Polyatomic photodissociation can also be treated by a similar formalism.
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