Chemical mass balance source apportionment of PM 10 and TSP in residential and industrial sites of an urban region of Kolkata, India

Abstract

Daily average PM 10 (particulate matter which passes through a size selective impactor inlet with a 50% efficiency cut-off at 10 μm aerodynamic diameter), TSP (total suspended particulate matter) and their chemical species mass concentrations were measured at residential and industrial sites of an urban region of Kolkata during November 2003–November 2004. Source apportionment using chemical mass balance model revealed that the most dominant source throughout the study period at residential site was coal combustion (42%), while vehicular emission (47%) dominates at industrial site to PM 10. Paved road, field burning and wood combustion contributed 21%, 7% and 1% at residential site, while coal combustion, metal industry and soil dust contributed 34%, 1% and 1% at industrial site, respectively, to PM 10 during the study period. The contributors to TSP included coal combustion (37%), soil dust (19%), road dust (17%) and diesel combustion (15%) at residential site, while soil dust (36%), coal combustion (17%), solid waste (17%), road dust (16%) and tyre wear (7%) at industrial site. Significant seasonal variations of the particulate matters have been observed during the study period. In the monitoring sites total carbon, organic carbon and iron were found to be the marker species of road dust, while organic carbon, total carbon, chloride and sulfate have been observed as the marker species of soil dust in TSP.