Chemical interactions of solar wind with cometary nuclei and comae

Abstract

Solar wind particles, especially H, C, N, O, S, and P-ions, may undergo specific chemical reactions with gaseous or solid matter of comets when in the energy region of a few 10 to some eV. Each component of the solar wind, even if not chemically reactive itself, creates a multiplicity of energetic secondary particles by knock-on processes with the cometary matter. These are responsible for the majority of the so called “hot” chemical processes. Endothermic reactions with high activation energy and atom molecule interactions are possible and may add to the classical exothermic ion-molecule or radical reactions. Other sources of hot atoms or ions in comets are: cosmic rays, acceleration or pick-up processes and turbulences in comae and gas or dust tails, and photon absorption induced dissociation. The products of hot chemical reactions, short period comets experience on their orbits, add to those formed in the individual component ice or dust grains by strong fluxes of energetic particles in times prior to the accretion to a comet.