Abstract
Ionic equilibria of ferrous chloride solutions were analyzed by considering chemical equilibria, mass, and charge balance equations. The activity coefficients of solutes and water activity were calculated with the Bromley equation. The equilibrium constants for the formation of Fe(II) complexes were determined from the reported thermodynamic data. The effects of HCl and FeCl2 concentration on the distribution of Fe(II) species and on the activity of HCl were estimated by applying ionic equilibria. The solvent extraction behavior of FeCl2 with Alamine 336 was explained with the distribution of Fe(II) species. The predicted pH values for FeCl2-HCl-H2O system agreed well with those experimentally measured at 25°C.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
