Abstract
The mechanism of the sliding wear of metals in corrosive media was investigated. In particular, the role of chemical heterogeneities on chemical interactions between the sliding surface and its environment was studied using 2024 aluminum alloy and sodium chloride solutions of varying pH and NaCl concentration. Sliding wear tests with a cylinder-on-cylinder geometry were performed at a sliding speed of 1 m min −1 and a normal load of 9.8 N (1 kgf). The results show that at pH = 0 and pH = 14, the wear rate is dominated by the dissolution of aluminum into the NaCl solution. In the intermediate pH range, the wear rate is shown to be controlled by the conjoint actions of corrosion and delamination wear. Microscope examination of the worn specimens by means of a scanning electron microscope further confirms that the mode of corrosion is of a localized nature.
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