Chemical durability of lead silicate glass in HNO3, HCl and H2SO4 aqueous acid solutions

Abstract

Abstract Acid dissolution of silicate glasses with different lead contents was rigorously investigated. Aqueous solutions containing 0.5, 1, and 2 N HNO 3 , HCl and H 2 SO 4 were used to measure the durability of the glass probes. Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Inductively Coupled Plasma (ICP), X-ray Diffraction (XRD) and weight loss analyses were used to evaluate the morphological/compositional changes of the probes, the ash deposit, and the aqueous solutions produced due to the dissolution of the glass specimens. Empirical results showed that any increase in the lead content of the probes deteriorated the durability of the glasses by accelerating the hydrolysis of the silica network. ZrO 2 and TiO 2 additions had inverse effect and improved the chemical durability and the practical life-time of the lead glasses.