Abstract
AbstractThe six‐membered ring Hg3Te3 of [Hg3Cl3(μ‐TePh)3]·2 DMSO {(Ph = C6H5; DMSO = (CH3)2SO} was opened by redissolution with DMSO, reacting with Co[Hg(SCN)4] and affording polymeric $ {\rm [(DMSO)_2 Co(NC \overline{S)_4(Hg}-TePh)_2]_{\rm n} }$. The monoclinic novel compound belong to the space group P21/n and assembles in a bidimensional lattice tetrahedral HgII(SCN)2Te2‐ and octahedral CoII(NCS)4(DMSO)2‐chains linked trough SCN bridges along the crystallographic axis b and diagonally to the ac axes. The structure of [(DMSO)2Co(NCS)4(Hg—TePh)2]n is limited by the DMSO ligands in the axial positions of the Co‐octahedrons.
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