Chemical composition of hard- and softrock groundwaters from central Norway with special consideration of fluoride and Norwegian drinking water limits

Abstract

Groundwaters from crystalline and metamorphic rocks (hardrocks) and from Quaternary deposits, i.e., alluvial and glacial deposits (softrocks) from the counties of Nord-Trondelag and Sor-Trondelag were analyzed for major and minor elements and ions including fluoride. The median concentration of F− in water from the hardrock aquifers is 0.28 mg/l (14.7 μeq/l) in contrast to water from softrock aquifers in which it is found to be 0.05 mg/1 (2.6 μeq/l). More importantly, ca. 15% of the locations where water was abstracted from hardrock wells contain 1.5 mg/l (78.9 μeq/l) F− or more. Thus, 15% of all hardrock wells returned F− results that are at or above the maximum recommended value for drinking water. Of the softrock wells, none are above 1 mg/l. Geologists would normally expect higher F−contents in groundwaters derived from acid rocks, e.g., in granitic or gneissic areas. When comparing the host lithology with the observed F−contents, however, no clear relationship between F− content and lithology is visible. The highest observed F− values actually occur in gneissic host rocks. However, wells drilled in amphibolites/greenstones, mica schists, calcareous rocks, and sedimentary rocks all returned some analytical results above 1.5 mg/l F−. These results suggest that all hardrock wells drilled should be tested for F− and the users informed about the results and advised to take any necessary precautions. When applying the recently proposed Norwegian drinking water limits to our data, 51% of all softrock well waters and 56% of all hardrock well waters are unfit for consumption without prior treatment, although we analyzed only for about half of the proposed elements/parameters. This result seriously questions the concept of fixed action levels—many of them with totally unproven health implications—for so many parameters/elements for hardrock groundwaters.