Abstract
A number of newly Ln-N bond valence parameters were quantitatively estimated, which allowed us to obtain all Ln-N bond lengths with different coordination numbers in metal organic complexes. Twenty linear correlations among the mean bond valence parameters of Ln-O, Ln-N, Ln-S, Ln-Cl and Ln-C bonds of metal organic complexes have been well established and denoted by a set of linearity equations, which provides us a useful method to determine the bond valence parameters of other type Ln-atom bonds in coordination chemistry. The present work shows us a novel approach to deeply understand the chemical bonding characteristics between Ln and the ligands in various metal organic complexes.
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