Chemical assembling of silica surface using a reaction of catalytic hydrosilylation

Abstract

Chemical assembling of the silica surface modified by dimethylchlorosilane was performed by the catalytic hydrosilylation of 1,3-divinyl-1,1,3,3-tetramethyldisiloxane, α-methyl styrene, acetophenone, allyl butyl and allyl glycidyl ethers with dimethylchlorosilane. The effect of the nature of complexes of platinum, palladium, rhodium and ruthenium on the parameters of hydrosilylation was studied. It was shown that the maximum rate of hydrosilylation was observed in the reaction with allyl glycidyl ether, and minimum, with α-methylstyrene; the most effective catalyst of hydrosilylation was [Rh(CO)2(acac)].