Chemical and structural changes of ocote pine (Pinus oocarpa) wood caused by thermal modification

Abstract

Thermal modifications alter the physical properties and improve the natural durability of wood without using chemical impregnation processes being an environmentally friendly alternative; these improvements could be made due to changes in the internal wood structure. In this investigation, changes caused to the chemical composition and microstructure of wood Pinus oocarpa by thermal modification at 170 and 190 °C were evaluated. The thermal treatment was carried out in a prototype chamber operated during the modification steps under a steam atmosphere, with a continuous flow without pressure. The evaluation of chemical changes was performed following the TAPPI standards. Using Fourier transform infrared spectroscopy (FTIR) and optical microscopy, the wood microstructure was characterized. The results showed a decrease in holocellulose contents by 7% at 170 °C and by 9% at 190 °C; lignin contents increased at 170 °C (6%) and at 190 °C (8%) and extractives were increased by 8% (170 °C) and 13% (190 °C); the changes obtained by the spectra were related to the C-H deformation in cellulose and hemicelluloses and the complex bonds of lignin carbohydrates of the -CH3 (lignin) and CH2 (carbohydrates) groups and organic acids released during thermal modification. Thickness of tracheid walls decreased in earlywood 8% (170 °C) and 22% (190 °C) and in latewood 11% (170 °C) and 14% (190 °C); lumen diameters increased in earlywood to 170 °C (14%) and 190 °C (48%) and in latewood in 14% (170 °C) an in 20% (190 °C). At 190 °C, the cell alterations were higher. Pinus oocarpa was thermally modified at 170 °C showing better wood quality in its internal structure.