Abstract

Direct-land application of liquid hog manure is the most common practice for recycling this type of waste. However, liquid hog manure not only contains valuable agronomic substances, it also includes substances that may pose serious environmental concerns. Pyrolysis-Field Ionization Mass Spectrometry(Py-FIMS), 13C Nuclear Magnetic Resonance (13C NMR), and Fourier-Transform Infra-Red (FTIR) were spectroscopy methods used to characterize colloidal fractions separated from three liquid hog manures. The spectroscopic data revealed that the colloids in the liquid manures contain relatively high concentrations of sterols(between 10.1 and 12.7% of Total Ion Intensity (TII)), which may have originated from animals and plants as well as from fortified feeds. Other significant colloid components, as percentages of TII, are lipids (5.3 to 11.9%), free fatty acids (3.4 to 9.5%), carbohydrates (2.5 to 6.0%), peptides (3.5 to 4.9%), n-alkylaromatics (2.9 to 4.0% C), N-compounds (3.1 to 4.7%), and phenols (2.5 to 4.0%). The presence of relatively high concentrations of sterols and phenols indicate that liquid hog manure has a high propensity for contributing to the contamination of soils and surface and subsurface waters.

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