Chemical and physical properties of cyclone fly ash from the grate-fired boiler incinerating forest residues at a small municipal district heating plant (6 MW)

Abstract

In Finland, the new limit values for maximal allowable heavy metal concentrations for materials used as an earth construction agent came into force in July 2006. These limit values are applied if ash is utilized, e.g. in roads, cycling paths, pavements, car parks, sport fields, etc. In this study we have determined the most important chemical and physical properties of the cyclone fly ash originating from the grate-fired boiler incinerating forest residues (i.e. wood chips, sawdust and bark) at a small municipal district heating plant (6 MW), Northern Finland. This study clearly shows that elements are enriched in cyclone fly ash, since the total element concentrations in the cyclone fly ash were within 0.2–10 times higher than those in the bottom ash. The total concentrations of Cd (25 mg kg −1; d.w.), Zn (3630 mg kg −1; d.w.), Ba (4260 mg kg −1; d.w.) and Hg (1.7 mg kg −1; d.w.) exceeded the limit values, and therefore the cyclone fly ash cannot be used as an earth construction agent. According to the leached amounts of Cr (38 mg kg −1; d.w.), Zn (51 mg kg −1; d.w.) and sulphate (50,000 mg kg −1; d.w.), the cyclone fly ash is classified as a hazardous waste, and it has to be deposited in a hazardous waste landfill.