Abstract
A homologous series of 1-O-acyl-D-glucopyranoses (acyl=caproyl, lauroyl, myristoyl, palmitoyl, or stearoyl) were obtained as the anomeric mixtures by condensation of the appropriate fatty acid chlorides with 2, 3, 4, 6-tetra-O-benzyl-α-D-glucopyranose, followed by catalytic hydrogenation : the α anomers were predominant in all the products. Their gas-liquid chromatographic and thin-layer chromatographic behaviors were examined to establish the linear relations of log rtR or Rf values to the acyl chain-lengths. From the anomeric mixtures, their α anomer components were isolated as crystallines by repeated recrystallization. Column chromatographic separation of the acetylated anomeric mixtures furnished the pure acetates of both anomers. The infrared nuclear magnetic resonance and mass spectral features were compared between the pairs of anomers.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
