Chemical Activity of Nascent Surfaces for Tribochemical Reactions of Lubricant Components.

Abstract

Boundary lubrication characteristics are strongly dependent on tribochemical reactions at the contact interface. There are multiple factors that contribute to the activity of tribochemical reactions and the complexity of this phenomenon. Here, we focused on nascent surfaces created by friction and aimed to clarify their chemical properties. To achieve this, we first developed a method based on a mass spectrometer that can sensitively detect molecular adsorption and reactions on a nascent surface. We used various organic compounds as adsorbates and friction materials such as steel, aluminum, gold, and ceramics and examined adsorption of the organic compounds on the nascent surfaces. The adsorption properties of the additives differed between steel metal oxide and nascent steel surfaces. For example, polar organic phosphates, which are extreme-pressure additives, were more easily adsorbed on oxide surfaces, whereas nonpolar organic sulfur compounds were more easily adsorbed on nascent steel surfaces. Alcohols and ethers also adsorbed on nascent aluminum surfaces, whereas olefins and benzene did not. Nascent gold surfaces showed high catalytic activity. Saturated hydrocarbons and fluorinated compounds, which are chemically inert, were also adsorbed on nascent ceramic surfaces, showing high activity. Hydrocarbon oils decomposed through the influence of frictional heat on a nascent steel surface to generate hydrogen and methane. We applied reactive molecular dynamics to simulate the adsorption phenomenon on iron surfaces. As a result, the adsorption energy obtained by simulation and the experimentally determined adsorption activity correlated well. Thus, adsorption and reaction behaviors on nascent surfaces inferred by our method were theoretically supported. On the basis of the chemical properties of the nascent surfaces obtained here, it is possible to explain boundary lubrication phenomena.