Abstract
Manganese(II) enhanced spin-lattice relaxation rates (1/ T 1 p ) of 1H and 13C nuclei in quinoline-2-carboxylic acid, 8-methoxyquinoline-2-carboxylic acid, 8-hydroxyquinoline-2-carboxylic acid, 8-aminoquinoline-2-carboxylic acid, and 6-(hydroxymethyl)pyridine-2-carboxylic acid were measured in aqueous solution at various temperatures. Relative metal-nucleus distances were calculated from the r −6 dependence of 1/ T 1 p . The results indicate that the Mn 2+ ion in the 8-methoxyquinaldic acid chelate is coordinated to the carboxyl oxygen atom and the nitrogen atom but not t the methoxyl oxygen atom.
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