Abstract
AbstractAcetylacetone (Hacac) admitted as a gas to an ion source containing CoCl2 adsorbed on a field ionization/field desorption emitter produces the ion [Co(acac)Cl]+. Similar ions arising from interaction of adsorbed salt and a ligand admitted as a gas were found for CoCl2 and trifluoroacetyl acetone, and for FeCl2 and acetylacetone. The chelation process represents a new kind of reaction of chemisorbed species in field ionization mass spectrometry.
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