Chelating stability of an amphoteric chelating polymer flocculant with Cu(II), Pb(II), Cd(II), and Ni(II)

Abstract

The absorption spectra of Cu2+, Pb2+, Cd2+, and Ni2+ chelates of an amphoteric chelating polymer flocculant (ACPF) were measured by ultraviolet spectrophotometry, and their compositions and stability constants (β) were calculated. ACPF exhibited three apparent absorption peaks at 204, 251, and 285nm. The CSS− group of ACPF reacted with Cu2+, Ni2+, Pb2+, and Cd2+ to form ACPF–Cu2+, ACPF–Ni2+, ACPF–Pb2+, and ACPF–Cd2+ chelates, respectively, according to a molar ratio of 2:1. The maximum absorption peaks of ACPF–Cu2+, ACPF–Ni2+, ACPF–Pb2+, and ACPF–Cd2+ appeared at 319, 326, 310, and 313.5nm, respectively. The maximum absorption peaks of the chelates showed significant red shifting compared with the absorption peaks of ACPF. The β values of the ACPF–Cu2+, ACPF–Pb2+, ACPF–Cd2+, and ACPF–Ni2+ chelates were (1.37±0.35)×1012, (3.26±0.39)×1011, (2.05±0.27)×1011, and (3.04±0.45)×1010, respectively. The leaching rate of heavy metal ions from the chelating precipitates decreased with increasing pH. ACPF–Cu2+, ACPF–Ni2+, ACPF–Pb2+, and ACPF–Cd2+ were very stable at pH⩾5.6. Cu2+, Ni2+, Pb2+, and Cd2+ concentrations in the leaching liquors were lower than the corresponding limits specified by the Integrated Wastewater Discharge Standard of China.