Abstract

Chelating polymer bearing 2-(2-diazolylazo)phenol moiety was synthesized and its metal adsorption properties for 6 divalent heavy metal ions (M2+): Co2+, Ni2+, Cu2+, Zn2+, Cd2+ and Pb2+ were investigated. The polymer changed color from orange yellow to blue or to red violet with its chelation to Cu2+ or to Ni2+, respectively. The maximum capacity of the polymer for Cu2+ was found to be 1.35 meq/ginpH 5.71 solution. The degrees of saturation of the capacity of the polymer after shaking for 30 min were 71.3 and 83.6% for the adsorptions of Zn2+ and Cu2+, respectively. The capacity of the polymer for M2+ hardly varied with the presence of alkali or alkaline earth metal ions. The elimination of metals from the polymer-M2+ chelates was achieved with 4 mol/1 HCl or 4 mol/1 H2SO4 solution.

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