Abstract
The dynamics of transport of electrochemically generated deuterium across the electrode/electrolyte interphase was examined by slow scan (10 mV s −1) voltammetry. The investigation covers the potential range −1.2 to +0.4 V measured vs. an Ag/AgCl reference. It was found that a coupled, two-layer model of the interphase describes the observed behavior as a function of scan rate and electrolyte composition. The effect of chemisorbing species, e.g. CN − ions, as well as reactive species, e.g. SC(NH 2) 2, on the transport across the interphase is also discussed. Results are contrasted with those obtained for light water.
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